The first stereocontrolled synthesis of the unique calebassinine-1 skeleton has been developed utilising base-catalysed α-hydroxy ketone rearrangement as a key step.
G. Palmisano, B. Danieli, G. Lesma and M. Mauro, J. Chem. Soc., Chem. Commun., 1986, 1564 DOI: 10.1039/C39860001564
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