Issue 17, 1986

Regioselectivity of the amino-Claisen rearrangement. The rearrangements of N-allyl-9-methoxy-1-oxajulolidinium bromide and N-allyl-8-methoxylilolidinium bromide

Abstract

High regioselectivity was observed in the title rearrangements and the reactions were rationalized as occurring via a transition state which closely resembles the lowest energy valence-bond resonance form.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1308-1311

Regioselectivity of the amino-Claisen rearrangement. The rearrangements of N-allyl-9-methoxy-1-oxajulolidinium bromide and N-allyl-8-methoxylilolidinium bromide

K. Kaneko, H. Katayama, Y. Saito, N. Fujita and A. Kato, J. Chem. Soc., Chem. Commun., 1986, 1308 DOI: 10.1039/C39860001308

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