Issue 6, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Cyclisation of metal chain complexes: X-ray crystal structures of [Pt3W4(µ-CR)2(µ3-CR)2(CO)8(η-C5H5)4] and [Pt4W4(µ-CR)(µ3-CR)3(CO)8(η-C5H5)4](R = C6H4Me-4)

Gregory P. Elliott,   Judith A. K. Howard,   Christine M. Nunn  and  F. Gordon A. Stone  

Abstract

The pentanuclear metal complex [Pt3W2(µ3-CR)2(CO)4(cod)2(π-C5H5)2](R = C6H4Me-4, cod = cyclo-octa-1,5-diene) reacts with [W([triple bond, length half m-dash]CR)(CO)2(η-C5H5)] to give [Pt3W4(µ-CR)2(µ3-CR)2(CO)8(η-C5H5)4], and the latter with [Pt(C2H4)3], prepared in situ from [Pt(cod)2], yields [Pt4W4(µ-CR)(µ3-CR)3(CO)8(η-C5H5)4] containing a Pt4W4 ring; the structures of these metal cluster complexes have been established by X-ray diffraction.

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Article information

DOI
https://doi.org/10.1039/C39860000431
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 431-433

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Cyclisation of metal chain complexes: X-ray crystal structures of [Pt3W4(µ-CR)2(µ3-CR)2(CO)8(η-C5H5)4] and [Pt4W4(µ-CR)(µ3-CR)3(CO)8(η-C5H5)4](R = C6H4Me-4)

G. P. Elliott, J. A. K. Howard, C. M. Nunn and F. G. A. Stone, J. Chem. Soc., Chem. Commun., 1986, 431 DOI: 10.1039/C39860000431

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