The reaction of MoMe(CO)3(η-C5H5) with LiEt3BH results in initial formation of the anionic formyl Mo(CHO)Me(CO)2(η-C5H5)–(3) which undergoes subsequent successive rearrangements to the hydrido acyl Mo[C(O)Me]H(CO)2(η-C5H5)–(4) and the η2-acetaldehyde complex Mo(η2-MeCHO)(CO)2(η-C5H5)–(2).
J. T. Gauntlett, B. F. Taylor and M. J. Winter, J. Chem. Soc., Chem. Commun., 1984, 420 DOI: 10.1039/C39840000420
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