Methanethialo S-Oxide was intercepted as an intermediate during the reaction of methanesulphinyl chloride and N,N-dimethylmethanamide (DMF), which afforded S-methyl methanesulphonothioate and S-(chloromethyl) methanesulphonothioate.
F. Freeman and M. C. Keindl, J. Chem. Soc., Chem. Commun., 1984, 138 DOI: 10.1039/C39840000138
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