Polymerization of ethylene took place over catalytic systems composed of Et2AlCl combined with metal chlorides in the absence of transition metal compounds, indicating that the Al–C bonds are the polymerization centres.
K. Soga, T. Shiono and Y. Doi, J. Chem. Soc., Chem. Commun., 1984, 840 DOI: 10.1039/C39840000840
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