Crystalliazation and X-ray studies have revealed the existence of a new class of clathrates in which the host tetraphenylene molecule uses crystallograpic C2 symmetery in the construction of the cagework; the clathration cavity of point symmetry S4 can accommodate guest species ranging in size from methylene chloride to cyclohexane.
N. Z. Huang and T. C. W. Mak, J. Chem. Soc., Chem. Commun., 1982, 543 DOI: 10.1039/C39820000543
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