Reaction of [MCl(NNMe2)2(PPh3)2]Cl (M = Mo or W) with [Bun4N]2[M′S4](M′= Mo, W) gives the complexes [S2M′S2M(NNMe2)2(PPh3)]; an X-ray crystal structure of the dinuclear complex with M = M′= Mo shows the molybdenum atoms to have distorted tetrahedral and trigonal bipyramidal geometries.
J. R. Dilworth and J. A. Zubieta, J. Chem. Soc., Chem. Commun., 1981, 132 DOI: 10.1039/C39810000132
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