Continuum, discrete and continuum–discrete models of solvation have been considered in order to rationalize the effect of solvent on the π*â†�n transition of methyl acetate. Whilst for solvents which give unspecific interactions the continuum model appears to be appropriate, for water a model which takes into account both specific and unspecific interactions is needed.
A. Raudino, F. Zuccarello and G. Buemi, J. Chem. Soc., Faraday Trans. 2, 1980, 76, 490 DOI: 10.1039/F29807600490
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