SCHEDULED MAINTENANCE:
The kinetics of oxidation of [Fe(CN)6]3– by nitrous acid at 25 °C have been studied. Reaction is acid catalysed at low acidities, [H+]= 0.01 mol dm–3, but the rate is independent of acidity at [H+]= 0.5 mol dm–3. Reaction is encounter controlled and occurs between [HFe(CN)6]3– and [NO]+.
J. C. Bates, P. Reveco and G. Stedman, J. Chem. Soc., Dalton Trans., 1980, 1487 DOI: 10.1039/DT9800001487
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