Experiments involving substituent and 15N labelling have ruled out cycloaddition and/or fragmentation mechanisms for the thermal transformation of perfluoroalkylpyridazines to mainly the corresponding pyrimidine derivatives.
R. D. Chambers, C. R. Sargent and M. Clark, J. Chem. Soc., Chem. Commun., 1979, 445 DOI: 10.1039/C39790000445
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