[m]Ferrocenophan-1-yl acetates undergo solvolysis in aqueous acetone by an SN1 mechanism, the rates increasing sharply through the series [3]- < FcCH(OAc)Me < [5]- < [4]-. Under these conditions, or in ethanol, [4]ferrocenophan-2-yl acetate is inert.
N. Cully, J. Park and W. E. Watts, J. Chem. Soc., Perkin Trans. 2, 1979, 947 DOI: 10.1039/P29790000947
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