Optically active N-alkylidenesulphinamides can be obtained from imino-Grignard reagents and sulphinate esters; the reaction is highly stereospecific and proceeds with inversion of chirality at sulphur.
M. Cinquini and F. Cozzi, J. Chem. Soc., Chem. Commun., 1977, 502b DOI: 10.1039/C3977000502B
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