2 H N.m.r. spectroscopy has been used to determine the stereochemistry of microbial hydrogenation of dehydrogriseofulvin to griseofulvin and microbial hydroxylation of the latter to 5′α-hydroxygriseofulvin, respectively.
Y. Sato, T. Oda and H. Saitô, J. Chem. Soc., Chem. Commun., 1977, 415 DOI: 10.1039/C39770000415
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