The continuous photolysis of [Cr(NH3)5Br]2+ in the charge transfer to metal region leads to reduction of CrIII and oxidation of Br–, e.g., producing Br2– in flash photolysis studies; the redox quantum yield was obtained as a function of irradiation wavelength and the redox threshold was found to be in the second ligand field quartet absorbtion band.
R. Sriram and J. F. Endicott, J. Chem. Soc., Chem. Commun., 1976, 683 DOI: 10.1039/C39760000683
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