Mono-olefins and 1,4-dienes have been synthesised with >99% stereochemical purity by the methylcopper-induced cross-coupling of dialkenylchloroboranes, formed from alkynes, with organic halides.
Y. Yamamoto, H. Yatagai, A. Sonoda and S. Murahashi, J. Chem. Soc., Chem. Commun., 1976, 452 DOI: 10.1039/C39760000452
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