Irradiation of a series of 2-hydroxymethyl-2H-azirine derivatives which contain good leaving groups affords N-vinylimines via a novel 1,4-substituent shift.
A. Padwa, J. K. Rasmussen and A. Tremper, J. Chem. Soc., Chem. Commun., 1976, 10 DOI: 10.1039/C39760000010
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