Issue 2, 1975

New routes to optically active phosphorus compounds. Asymmetric alkylation of phosphide anions

Abstract

The reaction of sodium methylphenylphosphide with (+)-(R)-1-chloroethylbenzene gives (–)-(SP)-(SC)-α-methylbenzylmethylphenylphosphine oxide after oxidation; the optical purities at phosphorus and carbon have been determined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 45-46

New routes to optically active phosphorus compounds. Asymmetric alkylation of phosphide anions

R. A. Naylor and B. J. Walker, J. Chem. Soc., Chem. Commun., 1975, 45 DOI: 10.1039/C39750000045

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