From the thermal decomposition of trans-3-deuterio-2-phenylcyclopropyl azide it is concluded that the styrene formation follows a stereospecific cis route to at least 97%.
G. Szeimies and J. Harnisch, J. Chem. Soc., Chem. Commun., 1973, 739b DOI: 10.1039/C3973000739B
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