Methods are described for the removal of carbon atom 32 from certain 32-functionalised lanosterol derivatives. It is shown unequivocally that the compounds thus obtained have the unnatural 14β-configuration.
T. J. Bentley, R. B. Boar, R. W. Draper, J. F. McGhie and D. H. R. Barton, J. Chem. Soc., Perkin Trans. 1, 1972, 749 DOI: 10.1039/P19720000749
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