Synthesis of the ABC ring system of the steroid batrachotoxin
Abstract
Cholic acid has been converted into methyl 3β-methoxy-3α,9α-oxido-11α-acetoxy-Δ7-cholenate (13), an intermediate embodying the ABC ring system of batrachotoxin.
Cholic acid has been converted into methyl 3β-methoxy-3α,9α-oxido-11α-acetoxy-Δ7-cholenate (13), an intermediate embodying the ABC ring system of batrachotoxin.
R. R. Schumaker and J. F. W. Keana, J. Chem. Soc., Chem. Commun., 1972, 622 DOI: 10.1039/C39720000622
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