Several 17β-acetoxy-17-substituted steroids undergo deacetoxylation on activated alumina at room temperature to afford olefinic products, whereas the parent carbinols remain unchanged under similar conditions.
R. Kanojia, S. Rovinsky and I. Scheer, J. Chem. Soc. D, 1971, 1581b DOI: 10.1039/C2971001581B
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