The importance of d-orbital participation and of π-back-donation in phosphorus oxyfluoride is discussed through the results of ab initio SCF–MO calculations.
A. Serafini, J.-F. Labarre, A. Veillard and G. Vinot, J. Chem. Soc. D, 1971, 996 DOI: 10.1039/C29710000996
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