A stereoelectronic requirement in a radical fragmentation reaction is demonstrated by the specific fission of the 4,5-bond in the 3β,5-cyclocholestan-6-yl radical.
A. L. J. Beckwith and G. Phillipou, J. Chem. Soc. D, 1971, 658 DOI: 10.1039/C29710000658
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