Treatment of porphyrins with thallium trifluoroacetate gives thallium(III) porphyrin chelates and, in the presence of trifluoracetic acid gives further products by oxidation at the porphyrin meso-positions.
K. M. Smith, J. Chem. Soc. D, 1971, 540 DOI: 10.1039/C29710000540
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