Issue 2, 1971

The ortho : para ratio in aromatic nucleophilic substitution

Abstract

Summary p-Nitrofluorobenzene reacts slightly faster than o-nitrofluorobenzene with methoxide ions in methanol, but under the same conditions the 2-fluorine atom in 2,4-difluoronitrobenzene is replaced faster than the 4-fluorine atom; an explanation is given to reconcile these observations.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 69-70

The ortho : para ratio in aromatic nucleophilic substitution

T. O. Bamkole and J. Hirst, J. Chem. Soc. D, 1971, 69 DOI: 10.1039/C29710000069

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