t-Butyl chlorocarbonyl and bromocarbonyl nitroxides, formed as by-products in reactions involving trihalogenomethyl radicals and nitrosobutane, have been characterised by their e.s.r. spectra, and by their reactions with primary alcohols and with dimethylamine: the e.s.r. study was facilitated by the use of a new spin trap, perdeuterionitrosobutane.
R. J. Holman and M. J. Perkins, J. Chem. Soc. D, 1971, 244 DOI: 10.1039/C29710000244
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