The action of carbon monoxide on aqueous hydrochloric acid solutions of RhIII produces initially RhIIICl5CO2–, which undergoes a further reductive carbonylation reaction to give RhI(CO)2Cl2–; the coordinated CO in the RhI complex is readily oxidized to CO2 by molecular oxygen.
J. A. Stanko, G. Petrov and C. K. Thomas, J. Chem. Soc. D, 1969, 1100 DOI: 10.1039/C29690001100
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