Semi-empirical one-electron molecular orbital calculations on platinum acetylene and olefin complexes indicate that the Dewar–Chatt–Duncanson model can be modified and extended to include acetylenic complexes and that these complexes are best represented as three-co-ordinate complexes of zerovalent platinum.
J. H. Nelson, K. S. Wheelock, L. C. Cusachs and H. B. Jonassen, J. Chem. Soc. D, 1969, 1019 DOI: 10.1039/C29690001019
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