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Issue 7, 2012
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Polyaspartamide vesicle induced by metallic nanoparticles

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Abstract

Polymer vesicles are being extensively studied to emulate self-assembly in biological systems and also use them in a variety of biological and industrial applications. This study demonstrates a novel strategy to prepare polymer vesicles in a pure aqueous medium by driving the micelle-to-vesicle transition with metallic nanoparticles. We synthesized poly(2-amino-2-hydroxyethyl aspartamide) (PAHA) substituted with octadecyl chains, which could form micelle-like self-aggregates in the aqueous medium and chemically bind with platinum precursors. Then, in situpolymerization of Pt nanoparticles within the PAHA self-aggregates generated polymer vesicles that possess nanoparticles within bilayers, because of the increase of the hydrophilic mass ratio to total mass of PAHA, f (w). This new strategy to prepare polymer vesicles would greatly serve to facilitate the control of self-assembly and ultimately improve the functionality of a wide array of polymer vesicles.

Graphical abstract: Polyaspartamide vesicle induced by metallic nanoparticles

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Publication details

The article was received on 16 Sep 2011, accepted on 15 Dec 2011 and first published on 09 Jan 2012


Article type: Paper
DOI: 10.1039/C2SM06763C
Citation: Soft Matter, 2012,8, 2237-2242

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    Polyaspartamide vesicle induced by metallic nanoparticles

    J. H. Jeong, C. Cha, A. Kaczmarowski, J. Haan, S. Oh and H. Kong, Soft Matter, 2012, 8, 2237
    DOI: 10.1039/C2SM06763C

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