Issue 23, 2020
From the journal:

Chemical Science

Ru-catalyzed isomerization of ω-alkenylboronates towards stereoselective synthesis of vinylboronates with subsequent in situ functionalization†

Guo-Ming Ho, ORCID logo a   Lucas Segura ORCID logo a  and  Ilan Marek ORCID logo *a  

* Corresponding authors

a Schulich Faculty of Chemistry, Technion – Israel Institute of Technology, Technion City 3200009, Haifa, Israel
E-mail: chilanm@technion.ac.il

Abstract

The stereoselective preparation of synthetically versatile vinylboronates from ω-alkenylboronates is achieved through a ruthenium-catalyzed isomerization reaction. A variety of di- and trisubstituted vinylboronates were conveniently produced and could be used as a new starting point for subsequent in situ remote functionalization through either a sequential Ru/Pd or Ru/Cu double catalytic system.

Graphical abstract: Ru-catalyzed isomerization of ω-alkenylboronates towards stereoselective synthesis of vinylboronates with subsequent in situ functionalization

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Article information

DOI
https://doi.org/10.1039/D0SC02542A
Article type
Edge Article
Submitted
05 May 2020
Accepted
26 May 2020
First published
26 May 2020
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2020,11, 5944-5949

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Ru-catalyzed isomerization of ω-alkenylboronates towards stereoselective synthesis of vinylboronates with subsequent in situ functionalization

G. Ho, L. Segura and I. Marek, Chem. Sci., 2020, 11, 5944 DOI: 10.1039/D0SC02542A

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