Issue 4, 2015
From the journal:

Catalysis Science & Technology

(Salicylaldiminato)Ni(ii)-catalysts for hydrosilylation of olefins†

Venu Srinivas,a   Yumiko Nakajima,*a   Wataru Ando,a   Kazuhiko Satoa  and  Shigeru Shimada*a  

* Corresponding authors

a National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan
E-mail: s-shimada@aist.go.jp

Abstract

A series of (salicylaldiminato)methylnickel complexes efficiently catalyse hydrosilylation of various olefins. The complexes are highly active for secondary hydrosilanes and exhibit excellent selectivity for monohydrosilylation. A possible mechanism, which includes a silylnickel complex as a key active species, is proposed.

Graphical abstract: (Salicylaldiminato)Ni(ii)-catalysts for hydrosilylation of olefins

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5CY00270B
Article type
Communication
Submitted
24 Feb 2015
Accepted
26 Feb 2015
First published
10 Mar 2015

Catal. Sci. Technol., 2015,5, 2081-2084

Permissions

Request permissions

(Salicylaldiminato)Ni(II)-catalysts for hydrosilylation of olefins

V. Srinivas, Y. Nakajima, W. Ando, K. Sato and S. Shimada, Catal. Sci. Technol., 2015, 5, 2081 DOI: 10.1039/C5CY00270B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements