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Issue 4, 2015
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(Salicylaldiminato)Ni(II)-catalysts for hydrosilylation of olefins

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Abstract

A series of (salicylaldiminato)methylnickel complexes efficiently catalyse hydrosilylation of various olefins. The complexes are highly active for secondary hydrosilanes and exhibit excellent selectivity for monohydrosilylation. A possible mechanism, which includes a silylnickel complex as a key active species, is proposed.

Graphical abstract: (Salicylaldiminato)Ni(ii)-catalysts for hydrosilylation of olefins

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Publication details

The article was received on 24 Feb 2015, accepted on 26 Feb 2015 and first published on 10 Mar 2015


Article type: Communication
DOI: 10.1039/C5CY00270B
Citation: Catal. Sci. Technol., 2015,5, 2081-2084

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    (Salicylaldiminato)Ni(II)-catalysts for hydrosilylation of olefins

    V. Srinivas, Y. Nakajima, W. Ando, K. Sato and S. Shimada, Catal. Sci. Technol., 2015, 5, 2081
    DOI: 10.1039/C5CY00270B

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