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Issue 55, 2014
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The synthesis and structure of chiral enamine N-oxides

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Abstract

Chiral enamine N-oxides have been synthesised by a diastereoselective intermolecular reverse-Cope cycloaddition reaction between chiral hydroxylamines and activated acetylenes. Their structures have been investigated by NMR, X-ray crystallography and computational methods.

Graphical abstract: The synthesis and structure of chiral enamine N-oxides

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Article information


Submitted
15 Oct 2013
Accepted
15 May 2014
First published
15 May 2014

Chem. Commun., 2014,50, 7336-7339
Article type
Communication

The synthesis and structure of chiral enamine N-oxides

I. A. O'Neil, M. McConville, K. Zhou, C. Brooke, C. M. Robertson and N. G. Berry, Chem. Commun., 2014, 50, 7336
DOI: 10.1039/C3CC47928E

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