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Issue 44, 2012
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Asymmetric H–D exchange reactions of fluorinated aromatic ketones

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Abstract

Chiral bicyclic guanidine catalyzes the asymmetric H–D exchange reactions. Up to 30% ee was achieved. DFT calculations were employed to elucidate and explain the origin of the reaction's stereoselectivity.

Graphical abstract: Asymmetric H–D exchange reactions of fluorinated aromatic ketones

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Article information


Submitted
27 Feb 2012
Accepted
30 Mar 2012
First published
30 Mar 2012

Chem. Commun., 2012,48, 5479-5481
Article type
Communication

Asymmetric H–D exchange reactions of fluorinated aromatic ketones

Y. Zhao, X. Lim, Y. Pan, L. Zong, W. Feng, C. Tan and K. Huang, Chem. Commun., 2012, 48, 5479
DOI: 10.1039/C2CC31443F

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