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Issue 41, 2014
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Chemical control of the monovalent–divalent electron-transfer phase transition in biferrocenium–TCNQ salts

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Abstract

An ionic molecular crystal of (1′,1′′′-dineopentylbiferrocene)(F1TCNQ)3 exhibits a first-order phase transition from a monovalent state (D+A3) to a divalent state (D2+A32−) at around 120 K. The transition was successfully controlled by modulation of the redox potentials using FnTCNQ (n = 0–2) and by chemical-pressure effects.

Graphical abstract: Chemical control of the monovalent–divalent electron-transfer phase transition in biferrocenium–TCNQ salts

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Article information


Submitted
19 Feb 2014
Accepted
24 Mar 2014
First published
24 Mar 2014

Chem. Commun., 2014,50, 5473-5475
Article type
Communication
Author version available

Chemical control of the monovalent–divalent electron-transfer phase transition in biferrocenium–TCNQ salts

T. Mochida, Y. Funasako, K. Takazawa, M. Takahashi, M. M. Matsushita and T. Sugawara, Chem. Commun., 2014, 50, 5473
DOI: 10.1039/C4CC01296H

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