Reaction of Mo(SBut)4 or Mo(SBut)2(CNBut)4 with CuBr (CNBut)3 or ‘Pd(CNBut)2’ gives mixed d4–d10 bimetal compounds; X-ray crystallographic studies have confirmed the presence of a highly delocalized MoS2Cu core in two conformational isomers of (ButNC)4Mo(µ-SBut)2CuBr.
S. Otsuka, N. Okura and N. C. Payne, J. Chem. Soc., Chem. Commun., 1982, 531 DOI: 10.1039/C39820000531
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