High-performance self-powered β-Ga2O3 asymmetric Schottky barrier deep-ultraviolet photodiode

Abstract

Self-powered deep-ultraviolet (DUV) photodetectors are highly desirable for low-power and easily integrated optoelectronic applications. In this work, we design Al/p-type β-Ga2O3/Ti/Au photodiodes incorporating asymmetric Schottky barriers (ASB) to realize self-powered DUV detection with a built-in potential (Vbi) of 0.950 V. The opposing built-in electric fields generated by the ASB configuration effectively suppress the dark current to 9.4×10^-13 A. Under illumination, the Vbi remains effective to provide the driving force required for self-powered operation. Meanwhile, the reduced depletion width at the metal–semiconductor interfaces further enhance photocarrier transport and collection. Benefiting from these effects, the devices operate in a self-powered mode, exhibiting a responsivity of 42.87 mA/W, and a detectivity of 2.1×10^12 Jones, with rise and decay time of 40 and 240 ms, respectively. These results demonstrate that ASB provide an effective strategy for developing high-performance self-powered DUV photodetectors.

Article information

Article type
Paper
Submitted
28 Dec 2025
Accepted
15 Jun 2026
First published
16 Jun 2026

J. Mater. Chem. C, 2026, Accepted Manuscript

High-performance self-powered β-Ga2O3 asymmetric Schottky barrier deep-ultraviolet photodiode

W. Wang, C. Liu, Z. Wu, D. Chen, N. Jia, Q. Sai, D. Guo, X. Dong, K. H. L. Zhang, H. Qi, W. Tang and Z. Fang, J. Mater. Chem. C, 2026, Accepted Manuscript , DOI: 10.1039/D5TC04527D

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