Improved ON/OFF Ratio in Interface-Type Memristors with Ion Irradiation-Induced Large Schottky Barrier for Neuromorphic Computing

Abstract

As a cutting-edge research direction in neuromorphic devices, interface-type (IT) memristors with leveraging interfacial engineering for resistive switching owing to the filament-free switching, low power dissipation, and high scalability. However, the trap states governing the interfacial Schottky barrier often exhibit a discrete and stochastic distribution. In this paper, the ion irradiation technology is used to control the interface Schottky barrier by regulating the defects near the surface of Nb:SrTiO 3 (NSTO). The device with the fluence of 1×10 12 cm -2 maintains good stability, excellent cyclic endurance characteristics and increases the on/off radio by an order of magnitude (from 10 5 to 10 6 ). Meanwhile, it can well simulate the synaptic function and in the neurological system, the recognition accuracy of images reaches 94.4%. These results indicate that ion irradiation can improve the resistance of IT memristors and be used in artificial synapses to establish the next generation of neural morphology calculation.

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Article information

Article type
Paper
Submitted
14 Oct 2025
Accepted
24 Dec 2025
First published
30 Dec 2025

J. Mater. Chem. C, 2026, Accepted Manuscript

Improved ON/OFF Ratio in Interface-Type Memristors with Ion Irradiation-Induced Large Schottky Barrier for Neuromorphic Computing

R. Wang, J. Su, Y. Liu, M. Xu, M. Zhang, P. Shan, W. Kong, Y. Li, H. Wu and T. Liu, J. Mater. Chem. C, 2026, Accepted Manuscript , DOI: 10.1039/D5TC03702F

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