Effect of externally applied pressure on rechargeable alkaline zinc batteries at limited depth of discharge

Abstract

Rechargeable alkaline zinc batteries (AZBs) are being actively researched for grid-scale energy storage due to their safety, low toxicity, abundance, low cost, and ease-of-production. However, numerous studies on alkaline Zn–MnO₂ batteries have shown that issues such as heterogeneous Zn deposition, passivation, dendrite formation, hydrogen evolution, and formation of chemically irreversible byproducts on the electrode surfaces still limit their rechargeability. Several mitigating strategies have been proposed to improve the rechargeability of alkaline Zn–MnO₂ batteries, but the effect of pressure on electrochemical behavior has not been systematically investigated. In this paper, we demonstrate that an externally applied pressure at 20% MnO₂ depth-of-discharge (DOD_MnO2) has a profound effect on impedance, electrochemical cycling behavior, and materials morphology of alkaline Zn–MnO₂ batteries. Better electrochemical performance and improved morphology were achieved at 2.12 MPa pressure compared to 0.05 MPa pressure. Moreover, we examined the effect of externally applied pressure from 0 to 5.05 MPa before cycling and found that charge transfer resistance decreases significantly with pressure. Furthermore, we reported stable electrochemical cycling of MnO₂‖MnO₂ symmetric cells for 500 hours at 20% DOD under 2.12 MPa pressure. Our efforts in understanding the effect of pressure could help design high performance and durable rechargeable alkaline Zn–MnO₂ batteries for grid-scale energy storage.