Whispering Gallery Mode study of phase transition and shape change in liquid crystal droplets

Abstract

We demonstrate that the Whispering Gallery Mode (WGM) lasing spectroscopy is a versatile high resolution tool to study the structure of interfaces of liquid crystalline (LC) droplets immersed in an immiscible fluid, such as water. The eigenfrequencies of WGMs in spherical microcavities are very sensitive to the refractive index profile in the nanometer thin interfacial region. This makes it possible to detect interfacial phenomena and temperature change in LC droplets with interferometric accuracy. We use 10 -30 μm diameter droplets of a nematic liquid crystal labeled with a fluorescent dye and floating in water as an optical microcavity that sustains the WGMs. At the isotropic-nematic transition we observe wetting of the droplet's interface by a nanometer-thin layer of paranematic LC. Just below this transition, we observe red-shift and strong fluctuations of WGM spectra just before spherical droplet elongates into a fiber. The experiments are modeled with Finite-Difference Time-domain (FDTD) analysis of WGMs in nematic droplet and we find a very good qualitative agreement.