Delamination and out-of-plane deformation in drying colloidal suspensions

Abstract

A drop of a colloidal suspension placed on a substrate forms a solid particle deposit as it dries. As water evaporates, large gradients in pore pressure inside the porous deposit cause shrinkage and stresses. The deposit cracks, then delaminates from the substrate, and bends out of plane, creating a striking three-dimensional structure. Previous models have attributed the out-of-plane deformation to pore pressure gradients through the deposit's thickness, a hypothesis our findings contradict. Through a combination of interference and confocal microscopy, we show that the final curvature strongly depends on the deposit thickness, with thinner deposits curving more. We propose a mechanism where the curvature is driven not by vertical pressure gradients, but by much larger radial gradients across the length of the deposit. The resulting in-plane differential shrinkage creates geometric frustration that is resolved through out-of-plane buckling. We validate this mechanism using non-Euclidean plate simulations, which successfully reproduce the buckling behavior and the observed dependence of curvature on thickness.