Efficient Red Circularly-Polarized Phosphorescence from Pyrene Derivatives Mediated by Locked Axial Chirality Scaffold

Abstract

As a classic polycyclic aromatic hydrocarbon luminophore, pyrene exhibits considerable potential for optoelectronic applications yet faces challenges in achieving chiral luminescence, particularly long-lived red circularly polarized phosphorescence. In this work, we report a strategy for manipulating the axial chirality of binaphthalene to enable pyrene to achieve efficient circularly polarized luminescence and red circularly polarized phosphorescence. It is revealed that the locked axial chiral binaphthalene not only boosts overall intersystem crossing via its transient triplet excited state but also amplifies circularly polarized phosphorescence through mediating structural rigidity and transition dipole moments. Bright circularly polarized luminescence with a high quantum yield of 65.7 % and distinct red circularly polarized phosphorescence with a dissymmetry factor of 6.5×10^-3 and a persistent lifetime of 381.9 ms, are obtained. The outlined structure-property relationship provides insights into the design principle for developing efficient circularly polarized luminescent materials.