Mechanochemically assembled organometallic complexes: a mechanistic study

Lama Hamdouna; Gianmarco Pisanò; Andrew G. M. Rankin; Julien Trébosc; Laura Falivene; Ida Ritacco; Olivier Devos; Laurent Delevoye; Pascal Roussel; Lucia Caporaso; Luigi Cavallo; Steven P. Nolan; Olivier Lafon; Catherine S. J. Cazin

doi:10.1039/D6SC01038E

Mechanochemically assembled organometallic complexes: a mechanistic study

Lama Hamdouna,^ab Gianmarco Pisanò,

^a Andrew G. M. Rankin,

^c Julien Trébosc,

^c Laura Falivene,

^d Ida Ritacco,

^d Olivier Devos,^e Laurent Delevoye,^b Pascal Roussel,

^b Lucia Caporaso,^d Luigi Cavallo,

^f Steven P. Nolan,

^a Olivier Lafon

*^b and Catherine S. J. Cazin

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 289 - S3, 9000 Ghent, Belgium
E-mail: catherine.cazin@ugent.be

^b Univ. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181-UCCS-Unité de Catalyse et Chimie du Solide, 59000 Lille, France

^c Univ. Lille, CNRS, INRAE, Centrale Lille, Univ. Artois, FR2638 - IMEC – Fédération Chevreul, 59000 Lille, France

^d Department of Chemistry and Biology, University of Salerno, Via Papa Giovanni Paolo II 132, 84084 Fisciano (SA), Italy

^e Université Lille, CNRS, UMR 8516, Laboratoire Avancé de Spectroscopie pour les Intéractions la Réactivité et l’Environnement (LASIRE), Lille, France

^f KAUST Catalysis Center, Physical Sciences and Engineering Division, King Abdullah University of Science and Technology, 23955-6900 Thuwal, Saudi Arabia

Abstract

A combination of mechanical synthesis, solid-state analytical techniques (ssNMR, powder XRD, ATR-FTIR) and DFT calculations sheds light on the mechanisms operating in two organometallic solid-state syntheses and highlight the importance of workup protocols in mechanochemical syntheses. The data clearly indicate that product formation can occur during or post grinding.

Chemical Science

Mechanochemically assembled organometallic complexes: a mechanistic study

Abstract

Supplementary files

Article information

Download Citation

Permissions

Mechanochemically assembled organometallic complexes: a mechanistic study

Social activity

Search articles by author

Spotlight

Advertisements