Dibenziodolium salts have recently emerged as useful iodine (III)-type halogen bonding (XB) donors. However, although benziodolium salts with one less benzene ring are expected to exhibit different reactivity from dibenziodolium salts, their function as a XB donor has not been clarified. Herein, a new and simple synthetic method of benziodolium salts and their application as organic Lewis acids are reported.
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H. Hirai, A. Tsubouchi, K. Miyamoto, A. Yoshimura and A. Saito, Org. Chem. Front., 2026, Accepted Manuscript , DOI: 10.1039/D5QO01379H
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