PLATFORM UPDATE:
Two novel classes of 6-membered nitrogen phosphorus heterocyclic carbene (NPHC) complexes arise from the insertion of methylene or imidogen units into one C–C bond of azaphospholylidene complexes via reactions with H2C=PPh3 or LiN=AsPh3, respectively.
R. M. Kirk and A. Hill, Inorg. Chem. Front., 2026, Accepted Manuscript , DOI: 10.1039/D6QI00613B
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