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We report a click chemistry strategy for synthesizing N3-triazole- and 2′-O-triazole-substituted glycosylated uridines and RNA oligonucleotides from N3-propargyl and 2′-O-propargyl uridines. Using β-D-glucopyranosyl azide, site-selective glycosylation was achieved at nucleoside and oligonucleotide levels, providing defined glycoRNA mimics for structural and functional studies.
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J. Wei, B. Gai, C. Wu, L. Liu and L. Cheng, Org. Biomol. Chem., 2026, Accepted Manuscript , DOI: 10.1039/D6OB00597G
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