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We herein describe a dehydrogenative cycloisomerization-arylation reaction of N-propargyl carboxamides with aromatic compounds by hypervalent iodine(III)-catalysis using sulfonyl chloride and sulfoxide. Compared to conventional methods, this approach allows the use of inexpensive reagents and is applicable to a wide range of aromatic compounds.
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M. Shoji, Y. Umakoshi, Y. Iwanami, A. Tsubouchi, A. Yoshimura and A. Saito, Org. Biomol. Chem., 2026, Accepted Manuscript , DOI: 10.1039/D6OB00564K
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