Recent Progress of BiVO₄-based Photoanode for Photoelectrochemical Water Splitting

Abstract

Photoelectrochemical (PEC) system, which harvests abundant solar energy and stores it in the form of hydrogen energy, offers an efficient, environmentally friendly, and renewable solution to address global energy demands and environmental concerns. Monoclinic bismuth vanadate (BiVO₄) has attracted widespread attention over the past decades due to its earth abundance, non-toxicity, suitable band structure, and visible-light absorption capability. However, its practical PEC water oxidation performance remains severely hindered by the rapid recombination of electric charge, insufficient active sites, and intrinsic kinetic limitations. In this review, we summarize the recent advances in BiVO₄-based photoanodes for PEC water splitting. We first introduce the basic working mechanisms of PEC water oxidation and then delve into the primary factors restricting its efficiency. Subsequently, we summarize and analyze the latest modification strategies — including bulk engineering, surface engineering, and interface engineering-and elucidate their underlying mechanisms for improving charge separation and reaction kinetics. Finally, this paper looks ahead at the future development directions of BiVO₄-based photoanodes.