The composition detection method of electrolyte based on LIBS liquid-solid conversion and magnetic-spatial confinement

Abstract

Electrolyte composition plays a critical role in copper hydrometallurgy, directly affecting product quality, recovery efficiency, and process stability. Conventional detection techniques often suffer from complex workflows and elementspecific limitations, while direct LIBS analysis of liquids faces issues such as droplet splashing, weak emission signals, and poor repeatability. To overcome these challenges, we propose a LIBS method that integrates liquid-solid conversion, magnetic field confinement and spatial confinement. The electrolyte is frozen into a solid state, and a constructing magnetic field by using an annular electromagnetic coil, whose inner wall is designed to form a small cylindrical space to simultaneously provide magnetic-spatial confinement on plasma. By optimizing the structural performance of electromagnetic coil, the spectral performance of the frozen electrolyte under magnetic-spatial confinement is signifi-cantly improved. The proposed method achieves an average spectral enhancement factor of 11.96, while reducing RSD to 7.82% and increasing SBR to 122.16. Calibration curves show improved detection accuracy for Cu, Ca, and Na: the R² values increase from 0.804, 0.967, and 0.964 (without confinement) to 0.991, 0.995, and 0.989 (with magnetic-spatial confinement), respectively. The LoD of Cu, Ca, and Na decrease by 70.7%, 53.9%, and 27.9%, respectively. This study demonstrates a simple and cost-effective approach, which provide a promising strategy for rapid and accurate multi-element detection in metallurgical electrolytes.