Towards Stimulando Time-Resolved Infrared Spectroscopy to Study Intermittent Light-Stimulated CO2 Hydrogenation

Abstract

Resonant catalysis theory predicts that applying an intermittent stimulus, such as charge, strain, heat or light, at frequencies on the timescale higher than the catalytic turnover frequency, can enhance activity by orders of magnitude and improve selectivity. However, experimental evidence of resonant catalysis is unfortunately lacking. This is partly due to the fact that the effect of intermittent stimulation on catalysts and reaction intermediates is not well understood. To address this challenge, time-resolved "stimulando" spectroscopic methods are needed to observe catalysts under operating conditions, and during stimulation. Here, we use diffuse reflectance infrared Fourier-transform spectroscopy (DRIFTS) to study the effect of intermittent light stimulation on the catalytic hydrogenation of CO₂ over Ni-Ga-based catalyst materials as a model reaction. Previous research has shown that light can cause CO desorption and change the reactivity of formate intermediates during reaction. Since CO and formate species are believed to be active intermediates in CO₂ hydrogenation, understanding how intermittent light affects their binding energy and surface coverage can provide insights into how to effectively stimulate catalysts to possibly achieve resonant catalysis. Ni3-Ga/SrTiO3 catalysts were synthesized using incipient wetness impregnation and tested under CO2 hydrogenation reaction conditions. Stimulando DRIFTS measurements were performed using both steady-state and rapid-scan DRIFTS to study the effect of continuous and intermittent ultraviolet (UV) light stimulation. Steady-state DRIFTS revealed that the surface coverage of CO, formate, and carbonate intermediates decreased reversibly upon UV illumination, each exhibiting distinct timescales to reach steady state (ranging from seconds to minutes). Furthermore, rapid-scan DRIFTS with millisecond time resolution demonstrated that spectral changes generally occurred faster when switching UV light on compared to off in steady state experiments. However, when using intermittent light at 1 Hz on/off frequency, the rate of change for spectral features upon light switching on and off became comparable. This showcases the need to study catalyst stimulation under intermittent stimulation, to capture the dynamic response of the system at the limit cycle. Despite the observed changes in coverage of surface species, the CO2 hydrogenation performance of the catalyst was not significantly affected under the conditions studied herein. The stimulando spectroscopy method showcased here provides valuable insights for adjusting light stimulation parameters, such as intensity, duty cycle and light wavelength, paving the way to more effective catalyst stimulation.